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A series of phosphorus ylide (P-ylide) CO2 adducts were synthesized and first used as organocatalysts for CO2 transformation. Detailed studies on the cycloaddition reaction of CO2 with terminal epoxides show that P-ylide CO2 adducts are efficient metal-free and halogen-free organocatalysts to mediate this reaction under ambient conditions (25 °C, 1 atm of CO2). More importantly, the reactions

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Vol 6773

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